Seed crystal
A seed crystal is a small piece of single crystal material from
which a large crystal of, usually, the same material is to be
grown. The large crystal can be grown by dipping the seed into a
supersaturated solution, into molten material that is then
cooled, or by growth on the seed face by passing vapour of the
material to be grown over it.
Examples where the a seed crystal is used to grow large boules
or ingots of a single crystal include the semiconductor industry
where methods such as the Czochralski process or Bridgeman
technique are employed.
Single crystal
A single crystal, also called monocrystal, is a crystalline
solid in which the crystal lattice of the entire sample is
continuous and unbroken to the edges of the sample, with no
grain boundaries. The opposite of a single crystal sample is a
polycrystalline sample, which is made up of a number of smaller
crystals known as crystallites. Because of a variety of entropic
effects on the microstructure of solids, including the
distorting effects of impurities and the mobility of
crystallographic defects and dislocations, single crystals of
meaningful size are exceedingly rare in nature, and can also be
difficult to produce in the laboratory under controlled
conditions.
Because grain boundaries can have significant effects on the
physical and electrical properties of a material, single
crystals are of interest to industry, and have important
industrial applications. The most notable of these is the use of
single crystal silicon in the fabrication of semiconductors. On
the quantum scale that microprocessors operate on, the presence
of grain boundaries would have a significant impact on the
functionality of field effect transistors by altering local
electrical properties. Therefore, microprocessor fabricators
have invested heavily in facilities to produce large single
crystals of silicon.
Fabrication of single crystals usually involves the building of
a crystal layer by layer of atoms. Techniques to produce large
single crystals (boules) include slowly drawing a rotating "seed
crystal" in a molten bath of feeder material (as in the
Czochralski process and the Bridgeman technique). Some thin film
deposition techniques can be used for epitaxy, forming a new
layer of material with the same structure on the surface of an
existing single crystal.
Monocrystals are often made by Czochralski process, controlled
crystallization from the melted material.
Uses
Monocrystals of silicon and other semiconductors are important
for manufacture of integrated circuits.
Monocrystals of sapphire and other materials are used for lasers
and nonlinear optics.
Monocrystals of fluorite are sometimes used in the objective
lenses of apochromatic refracting telescopes.
Monocrystals of metals, especially superalloys, are used for
their special mechanical properties. Turbine blades of some gas
turbines are made of single crystal cast superalloy.
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